Step 1: DNA bond formation. Nucleotides in a DNA strand are joined by phosphodiester bonds. These bonds connect the 3'-hydroxyl group of one nucleotide to the 5'-phosphate group of the subsequent nucleotide, forming the sugar-phosphate backbone.
Step 2: Other bond types explained.
Hydrogen bond (Option B): These bonds occur between complementary nitrogenous bases (e.g., A-T, G-C) in double-stranded DNA, not within a single strand.
Glycosidic bond (Option C): This bond connects the sugar and nitrogenous base within a nucleotide.
Covalent bond (Option D): This is a broad classification; phosphodiester bonds are a specific instance of covalent bonds. \[ \therefore \text{The correct answer is: Phosphodiester bond.} \]