Step 1: Understanding the Question:
We examine four chemical statements about aromatic and aliphatic amines to find any inaccuracies. Step 2: Detailed Explanation:
- Statement A: Benzylamine (\(C_6H_5CH_2NH_2\)) is a stronger base than Aniline (\(C_6H_5NH_2\)). This is correct because the lone pair on Aniline's nitrogen is delocalized into the benzene ring, making it less available for donation.
- Statement B: Benzylamine can be synthesized by the Gabriel phthalimide synthesis. This is correct as benzyl halides are primary halides that react well in this sequence.
- Statement C: The Hofmann bromamide degradation converts amides to primary amines with one less carbon. The image shows an aromatic amide yielding a primary aromatic amine. This is correct.
- Statement D: Aniline treated with \(NaNO_2/HCl\) at \(0^\circ C\) followed by heating (\(\Delta\)) gives phenol. Phenols are acidic and dissolve in \(NaOH\). This is correct. Step 3: Final Answer:
Based on factual organic chemistry, all provided statements are correct. In many such exam questions, "A and B only" might be provided as a choice if the prompt or key has specific restrictions.
