Step 1: Since $\text{Var}(X_2)=4$ and $\text{Var}(X_3)=4$, the standard deviations are $\sigma_2=\sigma_3=2$. Define standardized variables $Z_2 = X_2/2$ and $Z_3=X_3/2$.
Step 2: Correlation is invariant under positive rescaling, so $\rho_{X_2X_3}=\rho_{Z_2Z_3}=\text{Cov}(Z_2,Z_3)$, since $Z_2,Z_3$ each have unit variance and their covariance directly equals their correlation.
Step 3: Now $\text{Cov}(Z_2,Z_3) = \text{Cov}(X_2/2, X_3/2) = \dfrac{1}{4}\text{Cov}(X_2,X_3) = \dfrac{1}{4}(1) = \dfrac{1}{4}$.
Step 4: Hence $\rho_{X_2X_3} = 0.25$.
\[\boxed{0.25}\]