To verify the accuracy of the provided assertions concerning historical scientific observations:
Assertion (I): "The Law of Octaves arranged elements based on ascending atomic number."
Analysis: John Newlands' Law of Octaves (1864) ordered elements by increasing atomic mass, not atomic number. It noted that every eighth element exhibited similar properties, analogous to musical octaves. Consequently, this assertion is false.
Assertion (II): "Meyer detected a repeating pattern in physical properties when plotted against atomic numbers."
Analysis: Julius Lothar Meyer contributed to the periodic table's development by plotting physical properties (e.g., atomic volume) against atomic masses, revealing a periodic trend. While atomic masses were used, the observed periodicity aligns with the concept of the periodic law. Therefore, this assertion is considered true regarding the development of periodic trends.
Conclusion: The accurate assessment is: "Assertion I is false, while Assertion II is true."
Bauxite is the principal ore used in the commercial extraction of aluminium. The Bayer’s process is used to refine bauxite into pure alumina, with caustic soda playing a crucial role in the initial stage of the process. Based on this, answer the following questions:
(a) Explain the reason behind the addition of caustic soda during the Bayer’s process.
(b) Write a balanced chemical equation representing the reaction between bauxite and caustic soda during the Bayer’s process.
Anil is a laboratory assistant in a college. He prepared nitric acid but stored it in a transparent container exposed to sunlight. After a few days, brown fumes were observed in the container and the acid turned slightly yellowish in colour.
(a) What was the error made by Anil while storing the acid?
(b) Why were brown fumes observed in the container?
(c) How can the yellowish tinge in the acid be removed?
State whether the following statements are True or False.
(a) Organic compounds having different molecular formula, but same structural formula are called isomers.
(b) A salt is a compound formed by partial or complete replacement of the hydrogen ion of an acid by a metal or electropositive ion.