The radius of the orbit for a hydrogen-like atom is given by the formula: rn = a0n2 Z-1, where rn is the radius of the nth orbit, a0 is the Bohr radius for the hydrogen atom, Z is the atomic number, and n is the principal quantum number. For hydrogen, a0 is given as 51 pm. Since Li++ resembles a hydrogen-like atom with Z = 3, we calculate:
Step 1: Identify Known Values Step 2: Calculate the Radius of the 5th Orbit
Using the formula:
r5 = 51 × (5)2 × 3-1
Calculate n2:
52 = 25
Substitute back:
r5 = (51 × 25) / 3 = 425 pm
Step 3: Validate the Computed Radius against the Range- The calculated radius of 425 pm fits exactly within the specified range of 425, 425.
Therefore, the radius of the 5th orbit of Li++ is 425 pm.