To find the length of the latus rectum of the hyperbola confocal with the given ellipse \(E: \frac{x^2}{36} + \frac{y^2}{25} = 1\), we need to first determine the parameters of the hyperbola and then calculate the latus rectum.
Therefore, the length of the latus rectum of the hyperbola is \(\frac{96}{\sqrt{5}}\).