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coordination number of ce...
Question:
medium
Coordination number of Cerium in ceric ammonium nitrate, \((NH_4)_2[Ce(NO_3)_6]\), is:
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Count six nitrate ligands, each binding through two oxygen atoms.
CPET - 2025
CPET
Updated On:
Jul 3, 2026
2
4
6
12
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The Correct Option is
D
Solution and Explanation
Ce4+ with 2 NH4+ counterions needs complex charge -2. 6 NO3- (-6 total) + Ce4+ = -2, confirms 6 nitrates. Bidentate binding gives CN=12.
\[\boxed{12}\]
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