Concept: Electric field at centre due to each charge is proportional to charge magnitude and directed radially. Find net field by vector addition of opposite corner contributions.
Step 1: Pair opposite corners: AC has +3q and -q, net field along diagonal proportional to 2q towards -q. BD has +4q and -2q, net field proportional to 2q towards -2q.
Step 2: Both diagonal fields have magnitude \(E_0\). Components: AC field = \((-\sqrt2 E_0, -\sqrt2 E_0)\), BD field = \((\sqrt2 E_0, -\sqrt2 E_0)\). Sum = \((0, -2\sqrt2 E_0)\), direction vertically downward, parallel to side CB.
Step 3: Write the final answer. \(\boxed{\text{Direction of electric field is along }CB}\)