Given the energy of an electron in an excited hydrogen atom as \( E_n = -0.85 \, \text{eV} \), determine the maximum number of possible transitions to lower energy levels.
This problem utilizes two fundamental principles of the Bohr model for hydrogen atoms:
Step 1: Identify the principal quantum number (\(n\)) of the excited state.
Using the provided energy \(E_n = -0.85 \, \text{eV}\) and the hydrogen atom's energy level formula, we solve for \(n\):
\[ -0.85 = -\frac{13.6}{n^2} \]Rearranging to find \(n^2\):
\[ n^2 = \frac{13.6}{0.85} \]Simplifying the fraction:
\[ n^2 = \frac{1360}{85} = 16 \]Taking the square root to find \(n\):
\[ n = \sqrt{16} = 4 \]The electron is in the 4th energy level, corresponding to the 3rd excited state.
Step 2: Compute the maximum number of allowed transitions from this level.
With \(n=4\), we apply the formula for the maximum number of spectral lines to find all possible transitions to lower levels (n=3, n=2, and n=1).
\[ \text{Number of transitions} = \frac{n(n-1)}{2} \]Substituting \(n=4\):
\[ \text{Number of transitions} = \frac{4(4-1)}{2} \]The calculation yields:
\[ \text{Number of transitions} = \frac{4 \times 3}{2} = \frac{12}{2} = 6 \]The maximum number of possible transitions to lower energy levels is 6.
The wavelength of spectral line obtained in the spectrum of Li$^{2+}$ ion, when the transition takes place between two levels whose sum is 4 and difference is 2, is
Spherical node shown in figure-1 is best represented by which point in figure-2. 