In conductive materials, charge density is maximized at points of greatest curvature, such as the apex of a cone, and diminishes with increasing surface area, as observed towards the base.
The charge density at the apex, denoted by \( \sigma_1 \), is the highest.
Charge densities at points \( Q, R, S \), which are symmetrically positioned at the base's periphery, are equivalent due to their larger surface area relative to the apex.
Consequently, the charge density relationship is established as:\[\sigma_1 > \sigma_2 = \sigma_3 = \sigma_4\]
Final Answer: The correct option is (2), \( \sigma_1 > \sigma_2 = \sigma_3 = \sigma_4 \).