To determine the change in surface energy during droplet coalescence, we analyze the relationship between droplet size and surface area. Consider the scenario where 1000 small droplets merge into a single larger droplet.
The process can be described as follows:
- Let \( r \) denote the radius of a single small droplet. The volume of one small droplet is \( V_{\text{small}} = \frac{4}{3}\pi r^3 \).
- With 1000 small droplets, the total initial volume is \( V_{\text{total}} = 1000 \times \frac{4}{3}\pi r^3 \).
- Upon coalescence, the volume of the resulting large droplet, with radius \( R \), remains constant: \( V_{\text{big}} = \frac{4}{3}\pi R^3 \).
- Equating the initial total volume to the final volume yields \( \frac{4}{3}\pi R^3 = 1000 \times \frac{4}{3}\pi r^3 \).
- Simplifying this equation, we get \( R^3 = 1000 \times r^3 \).
- Taking the cube root of both sides, we find the radius of the large droplet to be \( R = 10r \).
- Surface energy is directly proportional to surface area. The total surface area of the 1000 small droplets is \( A_{\text{small total}} = 1000 \times 4\pi r^2 \).
- The surface area of the single large droplet is \( A_{\text{big}} = 4\pi R^2 \). Substituting \( R = 10r \), we get \( A_{\text{big}} = 4\pi (10r)^2 = 400\pi r^2 \).
- The ratio of the surface area of the large droplet to the total surface area of the small droplets is \( \frac{A_{\text{big}}}{A_{\text{small total}}} = \frac{400\pi r^2}{1000 \times 4\pi r^2} = \frac{400}{4000} = \frac{1}{10} \).
- Consequently, the surface energy of the large droplet is \(\frac{1}{10}\) times the total surface energy of the initial small droplets.
Therefore, the surface energy is reduced to \(\frac{1}{10}th\) of its original value.