To find the molar mass of the carbonate M_2CO_3, we need to analyze the reaction between the carbonate and excess hydrochloric acid:
The reaction is as follows:
M_2CO_3 + 2HCl \rightarrow 2MCl + CO_2 + H_2O
From the reaction, 1 mole of M_2CO_3 produces 1 mole of CO_2.
We are given that 0.01186 moles of CO_2 are produced. Thus, 0.01186 moles of M_2CO_3 reacted.
The mass of M_2CO_3 used is 1 gram. Therefore, we use the formula for molar mass:
\text{Molar Mass of } M_2CO_3 = \frac{\text{Mass}}{\text{Moles}}
Substitute the given values:
\text{Molar Mass of } M_2CO_3 = \frac{1 \text{ gram}}{0.01186 \text{ moles}} \approx 84.3 \text{ g/mol}
Thus, the molar mass of M_2CO_3 is 84.3 \, \text{g/mol}, which matches one of the given options.
In conclusion, the correct answer is 84.3 \, \text{g/mol}.