List of top Chemistry Questions on Analytical Chemistry asked in JEE Main

Given below are two statements: 
Statement I: In the oxalic acid vs KMnO$_4$ (in the presence of dil H$_2$SO$_4$) titration the solution needs to be heated initially to 60°C, but no heating is required in Ferrous ammonium sulphate (FAS) vs KMnO$_4$ titration (in the presence of dil H$_2$SO$_4$). 

Statement II: In oxalic acid vs KMnO$_4$ titration, the initial formation of MnSO$_4$ takes place at high temperature, which then acts as catalyst for further reaction. In the case of FAS vs KMnO$_4$, heating oxidizes Fe$^{2+}$ into Fe$^{3+}$ by oxygen of air and error may be introduced in the experiment. 

In the light of the above statements, choose the correct answer from the options given below:

Given below are two statements: 

Statement I: In the oxalic acid vs KMnO$_4$ (in the presence of dil H$_2$SO$_4$) titration the solution needs to be heated initially to 60°C, but no heating is required in Ferrous ammonium sulphate (FAS) vs KMnO$_4$ titration (in the presence of dil H$_2$SO$_4$). 

Statement II: In oxalic acid vs KMnO$_4$ titration, the initial formation of MnSO$_4$ takes place at high temperature, which then acts as catalyst for further reaction. In the case of FAS vs KMnO$_4$, heating oxidizes Fe$^{2+}$ into Fe$^{3+}$ by oxygen of air and error may be introduced in the experiment. 

In the light of the above statements, choose the correct answer from the options given below:

During estimation of Nitrogen by Dumas' method of compound X (0.42 g) :
 
mL of $ N_2 $ gas will be liberated at STP. (nearest integer) $\text{(Given molar mass in g mol}^{-1}\text{ : C : 12, H : 1, N : 14})$