Question:medium

Write the major product in the following reaction: [H]

Show Hint

Wurtz = Two alkyl halides. Fittig = Two aryl halides. Wurtz-Fittig = One of each (Aryl + Alkyl).
Updated On: Jul 22, 2026
Show Solution

Solution and Explanation

Step 1: Reaction type identification.
The reaction between an aryl halide and an alkyl halide in the presence of sodium metal in dry ether is the Wurtz-Fittig reaction. It is used to couple aryl and alkyl groups.
Step 2: Reagents.
The image shows chlorobenzene ($C_6H_5Cl$) and chloromethane ($CH_3Cl$) reacting with sodium ($Na$) in dry ether. Sodium removes the halogen atoms from both reactants.
Step 3: Bond formation and equation.
Highly reactive organo-sodium intermediates (phenyl and methyl species) combine to form a new C-C bond: \[ C_6H_5Cl + CH_3Cl + 2Na \xrightarrow{\text{dry ether}} C_6H_5CH_3 + 2NaCl \]
Step 4: Product.
The major product is toluene (methylbenzene, $C_6H_5CH_3$), where the methyl group is directly attached to the benzene ring.
Was this answer helpful?
0