Step 1: Einstein’s photoelectric equation, \( E_{\text{kin}} = hu - \phi \), describes the energy balance. Here, \( E_{\text{kin}} \) is the photoelectron's kinetic energy, \( h = 6.626 \times 10^{-34} \, \text{J s} \) is Planck's constant, \( u \) is the incident radiation frequency, and \( \phi \) is the material's work function (minimum energy to eject an electron). The incoming photon energy is consumed by the work function, with any surplus becoming the electron's kinetic energy.
Step 2: Millikan's experiment confirmed Einstein's equation by measuring the stopping potential needed to halt photoelectrons. By measuring maximum photoelectron kinetic energy at different light frequencies, he verified the linear kinetic energy-frequency relationship predicted by Einstein's equation.