Step 1: Approach
Check the type of triangle first with Pythagoras, then find the angle.
Step 2: Type
$3^2+5^2=34$ and $7^2=49$. Since $34<49$ the largest angle is obtuse.
Step 3: Angle
Let the largest angle be $C$:
\[ 49=9+25-30\cos C\Rightarrow\cos C=-\frac{15}{30}=-\frac12 \]
So $C=120^\circ=\dfrac{2\pi}{3}$. This is option (C).
Final Answer:
The largest angle has cosine -1/2, so it is $\dfrac{2\pi}{3}$, option (C).
\[ \boxed{\frac{2\pi}{3}} \]