Step 1: Rule:
Look at nitrogen: one R group gives primary, two give secondary, three give tertiary.
Step 2: Apply:
t-Butylamine and isopropylamine each have one R on N, so both are primary. Primary amines have N-H hydrogens and can hydrogen bond; tertiary amines cannot.
Step 3: Result:
Statements (A), (B) and (C) hold, and only (D) fails.
Final Answer:
Statement D is false: isopropylamine is primary.
\[ \boxed{\text{(D) }\text{(D) is not correct}} \]