The question asks us to determine which of the following species is not stable among the given options. Let's evaluate each species:
Upon reviewing the stability of each species, $[SiCl_6]^{2-}$ stands out as the unstable compound. This is due to the fact that silicon typically does not stabilize its chlorides in a hexachloride form, unlike its fluorides and germanium's chlorides. Therefore, $[SiCl_6]^{2-}$ is the correct answer.
Conclusion: The species that is not stable is $[SiCl_6]^{2-}$.