The elevation of the boiling point, a colligative property, is contingent upon the quantity of particles (ions/molecules) present in a solution. CaCl$_2$ dissociates into three ions (Ca$^{2+}$ + 2Cl$^-$), thus introducing more particles than KCl (which yields two ions), and glucose and urea (both non-electrolytes, yielding one particle). Consequently, a CaCl$_2$ solution exhibits the highest boiling point.