Step 1: Classify by parent acid and base
CuSO4: weak base plus strong acid. NH4Cl: weak base plus strong acid. FeCl3: weak base plus strong acid. Na2CO3: strong base plus weak acid.
Step 2: Conclude
The anion of a weak acid is a base, so it picks up a proton from water. This is anionic hydrolysis and is seen in Na2CO3 only, option (B).
Final Answer:
Na2CO3.
\[ \boxed{\text{(B)}\ Na_2CO_3} \]