Which of the following reactions is used for the conversion of alkyl chloride to alkyl iodide?
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To avoid confusing the two halogen exchange reactions, use this mnemonic: Finkelstein is for Iodides (F and I don't match). Swartz is for Fluorides (S and F don't match).
Step 1: Know the goal.
We are swapping a chlorine on an alkyl chloride for an iodine.
Step 2: Recall the method.
Heating the chloride with sodium iodide in dry acetone does this. The NaCl that forms drops out and pushes the reaction forward.
Step 3: Name it.
This halogen swap is the Finkelstein reaction. Swartz makes fluorides, Fittig and Friedel-Crafts do other jobs.
\[ \boxed{\text{Finkelstein reaction}} \]
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