Question:medium

Which of the following does not obey the octet rule?

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Elements in Period 3 or higher can exceed the octet rule by utilizing their d-orbitals.
Updated On: Jan 13, 2026
  • \( SF_6 \)
  • \( H_2O \)
  • \( CO_2 \)
  • \( CH_4 \)
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The Correct Option is A

Solution and Explanation

Atoms strive to achieve a stable configuration of eight valence electrons by gaining, losing, or sharing electrons, as defined by the octet rule.

In the case of \( SF_6 \), sulfur accommodates twelve valence electrons by forming six bonds, thereby exceeding the octet rule: \[ \text{Valence electrons of S} = 6 + 6(1) = 12. \] 

Comparison: Molecules such as \( H_2O \), \( CO_2 \), and \( CH_4 \) adhere to the octet rule. Conversely, \( SF_6 \) violates the octet rule due to its expanded valence shell.

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