Question:medium

Which of the following ligands has two donor atoms?

Show Hint

Bidentate ligands form more stable complexes than monodentate ligands due to the chelate effect.
Updated On: Nov 26, 2025
  • \( Cl^- \)
  • \( I^- \)
  • Oxalate (\( C_2O_4^{2-} \))
  • \( H_2O \)
Hide Solution

The Correct Option is C

Solution and Explanation

Oxalate (\( C_2O_4^{2-} \)), a bidentate ligand, possesses two donor atoms for simultaneous metal ion coordination: the oxygen atoms within its carboxylate groups (-COO).

Structure: \[ \text{[O-C=O]} - \text{[O-C=O]}. \] 

In contrast, \( Cl^- \) and \( I^- \) are monodentate ligands, each with a single donor atom. Similarly, \( H_2O \) functions as a monodentate ligand, utilizing its single oxygen atom as the donor. 

Applications: Oxalate is a component of complexes such as potassium ferrioxalate (\( K_3[Fe(C_2O_4)_3] \)).

Was this answer helpful?
0