Question:medium

Which of the following is the correct order of acidic strength for the following compounds: HNO\(_3\), HClO\(_4\), and HClO\(_3\)?

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For oxyacids, the acidic strength generally increases with the number of oxygen atoms attached to the central atom and the electronegativity of the central atom. 

Updated On: Jan 14, 2026
  • HClO4 > HNO3 > HClO3
  • HNO3 > HClO3 > HClO4
  • HClO3 > HNO3 > HClO4
  • HClO4 > HClO3 > HNO3
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The Correct Option is A

Solution and Explanation

The strength of oxyacids, such as HNO3, HClO4, and HClO3, is determined by the central atom's electronegativity and the number of attached oxygen atoms. An increased number of oxygen atoms and a higher electronegativity of the central atom result in a stronger acid.
  • HClO4 exhibits the greatest acidity, attributed to chlorine's high electronegativity and the maximum number of bonded oxygen atoms.
  • HNO3 surpasses HClO3 in acidity due to nitrogen's greater electronegativity compared to chlorine and the presence of more oxygen atoms in nitric acid than in chlorous acid.
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