Question:medium

Which of the following is incorrect thermodynamical relation of Maxwell?

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Always check the sign carefully in Maxwell relations. The relation \(\left(\frac{\partial S}{\partial P}\right)_T\) contains a negative sign.
Updated On: May 19, 2026
  • \(\left(\dfrac{\partial T}{\partial V}\right)_S=-\left(\dfrac{\partial P}{\partial S}\right)_V\)
  • \(\left(\dfrac{\partial T}{\partial P}\right)_S=\left(\dfrac{\partial V}{\partial S}\right)_P\)
  • \(\left(\dfrac{\partial S}{\partial P}\right)_T=\left(\dfrac{\partial V}{\partial T}\right)_P\)
  • \(\left(\dfrac{\partial S}{\partial V}\right)_T=\left(\dfrac{\partial P}{\partial T}\right)_V\)
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The Correct Option is C

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