Which of the following ions exhibit same value of spin only magnetic moment? (A). \(\text{Ti}^{3+}\) (B). \(\text{Cr}^{3+}\) (C). \(\text{Mn}^{2+}\) (D). \(\text{Fe}^{3+}\) (E). \(\text{Sc}^{3+}\) Choose the most appropriate answer from the options given below.
Show Hint
Count unpaired electrons: Mn2+ and Fe3+ are both d5 with 5 unpaired electrons.
Step 1: Plan:
Write the electronic configuration of each ion by removing the 4s electrons first and then the 3d electrons.
Step 2: Configurations:
Ti ($3d^24s^2$) loses 3 electrons and becomes $3d^1$. Cr ($3d^54s^1$) becomes $3d^3$. Mn ($3d^54s^2$) loses two and becomes $3d^5$. Fe ($3d^64s^2$) loses three and becomes $3d^5$. Sc ($3d^14s^2$) becomes $3d^0$.
Step 3: Compare:
The half-filled $d^5$ set has five unpaired electrons, and both Mn(II) and Fe(III) carry it. So both have $\mu = \sqrt{5\times7} = 5.92$ BM.
Final Answer:
Mn(II) and Fe(III) have the same spin-only moment, option (C).
\[ \boxed{\text{(C) and (D) only}} \]