Question:medium

Which of the following has the least negative electron gain enthalpy?

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Electron gain enthalpy becomes more negative when an atom has a greater tendency to accept an electron. Chlorine has more negative electron gain enthalpy than fluorine due to lower inter-electronic repulsion.
Updated On: Jun 19, 2026
  • Oxygen
  • Fluorine
  • Chlorine
  • Sulphur
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The Correct Option is A

Solution and Explanation

Step 1: Defining electron gain enthalpy (EGE).
EGE quantifies the energy alteration when an atom acquires an electron; a more negative value signifies a stronger tendency to accept an electron.

Step 2: Contrasting halogens and chalcogens.

Fluorine and chlorine, being highly electronegative, exhibit very negative EGE values. Oxygen's EGE is less negative than both fluorine and chlorine.

Step 3: Influence of atomic dimensions.

Oxygen's smaller radius leads to significant electron-electron repulsion upon adding an extra electron, diminishing its negativity relative to larger atoms.

Step 4: Electronegativity pattern.

Electronegativity rises across a period, correlating with higher electron affinity; oxygen falls short of F and Cl.

Step 5: Supplementary check.

Sulphur, being larger than oxygen, possesses a more negative EGE, reinforcing that oxygen is the least negative among the given choices.

Step 6: Conclusion.

Thus, oxygen displays the least negative electron gain enthalpy.
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