Question:medium

What is the molecular geometry of the water molecule (H₂O)?

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When determining molecular geometry, remember that lone pairs affect the shape. Water has a bent shape due to the presence of lone pairs on oxygen.
Updated On: Nov 26, 2025
  • Linear
  • Trigonal planar
  • Bent
  • Tetrahedral
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The Correct Option is C

Solution and Explanation

Water (H₂O), a basic molecule, can have its structure elucidated via VSEPR theory (Valence Shell Electron Pair Repulsion theory). The analysis proceeds as follows:
1. Lewis Structure: - Oxygen contributes 6 valence electrons, and each hydrogen atom contributes 1. In H₂O, oxygen forms two single covalent bonds with the hydrogen atoms, leaving two lone pairs of electrons. 2. Electron Geometry: - The oxygen atom is surrounded by 4 electron pairs: 2 involved in bonding with hydrogen and 2 as lone pairs. VSEPR theory dictates that these 4 electron pairs orient themselves in a tetrahedral arrangement to minimize inter-pair repulsion. 3. Molecular Geometry: - Lone pairs, while influencing geometry, are not outwardly part of the molecular structure. Their presence exerts repulsion on the bonding pairs, resulting in a bent molecular configuration. - The bond angle between the hydrogen-oxygen-hydrogen atoms is approximately 104.5°, deviating from the ideal tetrahedral angle (109.5°) due to the repulsive forces exerted by the lone pairs. 4. Conclusion: - The water molecule exhibits a bent molecular geometry.
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