Question:medium

Which of the following elements of the 3d series of transition elements has the lowest \(\Delta_{a} H^\circ\)?

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The elements with a completely filled d-subshell, such as Zn, exhibit greater stability and lower enthalpy change, while other transition elements with partially filled d-subshells tend to have higher enthalpy changes.
Updated On: Jan 13, 2026
  • Sc
  • Cr
  • Cu
  • Zn
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The Correct Option is D

Solution and Explanation

\(\Delta H^\circ\) represents the standard enthalpy of formation. For transition metals, this value is influenced by electron configuration, elemental stability, and ionization energy.
- Scandium (Sc) and chromium (Cr) exhibit high ionization energies and enthalpy changes.
- Copper (Cu) possesses a stable electron configuration due to a full d-subshell, resulting in lower reactivity and a moderate \(\Delta H^\circ\).
- Zinc (Zn) also has a full 3d subshell and a stable electron configuration, making it the least reactive of the 3d transition elements and consequently exhibiting the lowest enthalpy change. Therefore, Zn has the lowest \(\Delta H^\circ\).
Consequently, Zn is the correct answer.
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