Step 1: Understanding the Concept:
The number of unpaired electrons is determined by the electron configuration of the valence shell using Hund's Rule.
Step 2: Formula Application:
Atomic numbers: N (7), O (8), F (9), Na (11).
Step 3: Explanation:
Nitrogen: $1s^2 2s^2 2p^3$. The three electrons in the $2p$ subshell occupy three separate orbitals. (3 unpaired)
Oxygen: $1s^2 2s^2 2p^4$. One $2p$ orbital is paired, two have single electrons. (2 unpaired)
Fluorine: $1s^2 2s^2 2p^5$. Two $2p$ orbitals are paired, one has a single electron. (1 unpaired)
Sodium: $[Ne] 3s^1$. (1 unpaired)
Step 4: Final Answer:
Nitrogen contains the maximum number of unpaired electrons.