Step 1: Recall electrode roles.
In electrolysis, positive metal ions move to the negative electrode, the cathode, and are reduced and deposited there.
Step 2: Check the statements.
Refining, electroplating, and turning electrical energy into chemical energy are all true uses of electrolysis.
Step 3: Spot the wrong one.
The statement that metal is deposited at the anode is false, since deposition happens at the cathode.
\[ \boxed{\text{Metal is deposited at anode, option 4}} \]