Question:medium

Which from following amines when heated with ethanolic KOH and chloroform does NOT produce foul smell ?

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Only primary amines give the carbylamine foul smell. N,N-dimethylaniline is tertiary.
Updated On: Oct 1, 2026
  • Benzenamine
  • N , N - Dimethyl aniline
  • Propan - 2 - amine
  • Phenylmethanamine
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The Correct Option is B

Solution and Explanation

Step 1: Count the hydrogens on nitrogen:
The reaction needs two N-H hydrogens to be lost, so the amine must have a free $-\text{NH}_2$.
Aniline: $\text{C}_6\text{H}_5\text{NH}_2$, primary.
Isopropylamine: $(\text{CH}_3)_2\text{CHNH}_2$, primary.
Benzylamine: $\text{C}_6\text{H}_5\text{CH}_2\text{NH}_2$, primary.
N,N-dimethylaniline: $\text{C}_6\text{H}_5\text{N(CH}_3)_2$, no N-H at all.

Step 2: Result:
Only the tertiary amine fails, so only it gives no foul-smelling isocyanide.

Final Answer:
Option (B). \[ \boxed{\text{N,N-Dimethylaniline (B)}} \]
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