Step 1: Rule:
Gabriel synthesis: primary aliphatic amines only.
Step 2: Eliminate:
Aniline is aromatic, dimethylamine is secondary, and the last option is tertiary.
Step 3: Answer:
Ethylamine, option (B).
Final Answer:
Option (B).
\[ \boxed{\text{(B) } \text{C}_2\text{H}_5\text{NH}_2} \]