Question:medium

Which among the following gases is adsorbed to greater extent at similar conditions of temperature and pressure if the adsorbent remains same?

Show Hint

Adsorption increases with ease of liquefaction (higher \(T_c\)). Cl\(_2\) has the highest \(T_c\) among these.
Updated On: Jun 4, 2026
  • N\(_2\)
  • Cl\(_2\)
  • H\(_2\)
  • O\(_2\)
Show Solution

The Correct Option is B

Solution and Explanation

Step 1: Understand the question.
At the same temperature and pressure, on the same adsorbent, we must find which gas is adsorbed the most.
Step 2: Recall the key rule.
For physical adsorption, the gas that is easiest to turn into a liquid is adsorbed the most. Ease of liquefaction is shown by the critical temperature.
Step 3: Link to critical temperature.
A higher critical temperature means stronger forces between the gas molecules, so it sticks to the surface more easily.
Step 4: Compare the gases.
The critical temperatures are roughly: $Cl_2$ about 417 K, $O_2$ about 154 K, $N_2$ about 126 K, $H_2$ about 33 K.
Step 5: Pick the highest.
Chlorine has the highest critical temperature, so it liquefies most easily and is adsorbed the most.
Step 6: Choose the answer.
The gas adsorbed most is $Cl_2$, which is option 2. \[ \boxed{Cl_2} \]
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