To solve this problem, first understand the chemical reaction involved and apply stoichiometry to find the volume of carbon dioxide (CO2) produced when propane (C3H8) is completely burnt at Standard Temperature and Pressure (STP).
The balanced chemical equation for the complete combustion of propane is:
\(C_3H_8 + 5O_2 \rightarrow 3CO_2 + 4H_2O\)
From the equation, we see that burning 1 mole of propane produces 3 moles of carbon dioxide. At STP, 1 mole of any gas occupies 22.4 liters.
Thus, when 5 liters of propane is burnt completely, 15 liters of carbon dioxide is produced at STP.
Therefore, the correct answer is: 15 litres.