Step 1: Boyle's Law.
Boyle's Law establishes an inverse relationship between pressure and volume at constant temperature: \( PV = \text{Constant} \). This aligns with option (III).
Step 2: Charles' Law.
Charles' Law states that at constant pressure, volume is directly proportional to temperature: \( \frac{V}{T} = \text{Constant} \). This matches option (I).
Step 3: Avogadro's Law.
Avogadro's Law indicates that volume is directly proportional to the number of moles: \( V \propto n \). This corresponds to option (IV).
Step 4: Graham's Law of Diffusion.
Graham's Law relates the rates of diffusion of gases to their molar masses using the formula \( \frac{T_1}{T_2} = \frac{M_2}{M_1} \). This matches option (II).
Step 5: Conclusion.
The correct pairings are (A) - (I), (B) - (II), (C) - (III), and (D) - (IV), which corresponds to option (3).
Final Answer: \[ \boxed{\text{(3) (A) - (I), (B) - (II), (C) - (III), (D) - (IV)}} \]
(Zn + 4HNO_3 Zn(NO_3)_2 + 2H_2O + 2NO_2)
32.5 g of zinc reacts with concentrated nitric acid as given in the above equation.
(a) How many moles of zinc was required in the reaction?
(b) Find the mass of nitric acid needed to react with 32.5 g of zinc.
(c) Find the volume of nitrogen dioxide liberated in (b).
(Atomic weight: H = 1, N = 14, O = 16, Zn = 65)