Question:medium

What is the oxidation state of \(S\) in the sulphur containing product of the following reaction?
\[ SO_3^{2-}(aq) + Br_2(l) + H_2O \longrightarrow \]

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In oxyanions, calculate oxidation state using the total charge of the ion. Sulphite \((SO_3^{2-})\) has sulphur in \(+4\) state, while sulphate \((SO_4^{2-})\) has sulphur in \(+6\) state.
Updated On: Jun 22, 2026
  • \(+6\)
  • \(+4\)
  • \(+2.5\)
  • \(+2\)
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Identify the species in the reaction.
The sulphur containing reactant is the sulphite ion $SO_3^{2-}$, and it reacts with bromine $Br_2$ in the presence of water. We must find the oxidation state of sulphur in the sulphur containing product.
Step 2: Recognise bromine as an oxidant.
Bromine is a good oxidizing agent. In water it pulls electrons from sulphite, oxidizing it. So sulphur in the product will be in a higher oxidation state than in $SO_3^{2-}$.
Step 3: Find the oxidation state of sulphur in sulphite.
In $SO_3^{2-}$, let sulphur be $x$. \[ x + 3(-2) = -2 \] \[ x - 6 = -2 \] \[ x = +4 \]
Step 4: Identify the oxidized product.
Oxidation of sulphite by bromine in water gives the sulphate ion $SO_4^{2-}$, which is the stable higher state. \[ SO_3^{2-} + Br_2 + H_2O \longrightarrow SO_4^{2-} + 2Br^- + 2H^+ \]
Step 5: Find the oxidation state of sulphur in sulphate.
In $SO_4^{2-}$, let sulphur be $y$. \[ y + 4(-2) = -2 \] \[ y - 8 = -2 \] \[ y = +6 \]
Step 6: State the answer.
The oxidation state of sulphur in the product $SO_4^{2-}$ is $+6$, matching the key.
\[ \boxed{+6} \]
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