Question:medium

In acidic medium, which of the following does not change its colour?

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In acidic conditions, \( \text{MnO}_4^- \) is stable and retains its purple colour, making it a reliable indicator in redox reactions.
Updated On: Nov 26, 2025
  • \( \text{MnO}_4^- \)
  • \( \text{MnO}_4^{2-} \)
  • \( \text{CrO}_4^{2-} \)
  • \( \text{FeO}_4^{2-} \)
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The Correct Option is A

Solution and Explanation

Analysis of ion behavior in acidic media is as follows: 1. \( \text{MnO}_4^- \) stability: \( \text{MnO}_4^- \) remains stable and retains its purple hue in acidic conditions due to a lack of further reactions. 2. \( \text{MnO}_2^{2-} \) behavior: \( \text{MnO}_2^{2-} \) disproportionates in acid, yielding purple \( \text{MnO}_4^- \) and colorless \( \text{Mn}^{2+} \). 3. \( \text{CrO}_4^{2-} \) conversion: \( \text{CrO}_4^{2-} \) transforms into \( \text{Cr}_2\text{O}_7^{2-} \) under acidic conditions, causing a color change from yellow to orange due to equilibrium shifts. 4. \( \text{FeO}_4^{2-} \) decomposition: \( \text{FeO}_4^{2-} \) breaks down into \( \text{Fe}^{3+} \), which is either colorless or pale yellow based on concentration. Consequently, \( \text{MnO}_4^- \) is the species among those listed that maintains its purple color in an acidic medium.

Final Answer: \[ \boxed{\text{MnO}_4^-} \]

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