To find the mole fraction of the solute in a 1.00\, m (molal) aqueous solution, we need to follow these steps:
Understand Molality: Molality (\(m\)) is defined as the number of moles of solute per kilogram of solvent.
Define the Given: A 1.00\, m solution means there is 1 mole of solute in 1 kg of water (the solvent).
Calculate Mole Fraction: Mole fraction of solute is calculated using the formula:
\[\text{Mole fraction of solute} = \frac{\text{Moles of solute}}{\text{Moles of solute} + \text{Moles of solvent}}\]
Calculate Moles of Solvent (Water): The molar mass of water is approximately \(18.01528 \, \text{g/mol}\). Therefore, moles of solvent (water) in 1 kg (1000 g) is:
\[\text{Moles of water} = \frac{1000 \, \text{g}}{18.01528 \, \text{g/mol}} = 55.51 \, \text{mol}\]
Substitute and Solve: Substitute the calculated values into the mole fraction formula:
\[\text{Mole fraction of solute} = \frac{1 \, \text{mol}}{1 \, \text{mol} + 55.51 \, \text{mol}} = \frac{1}{56.51} = 0.0177\]
Hence, the mole fraction of the solute in the 1.00\, m aqueous solution is 0.0177. This matches the given correct answer.
The freezing point depression constant (\( K_f \)) for water is \( 1.86 \, {°C·kg/mol} \). If 0.5 moles of a non-volatile solute is dissolved in 1 kg of water, calculate the freezing point depression.