Question:medium

What is the measurement of C-O-C bond angle in methoxymethane?

Updated On: Mar 27, 2026
  • 108$\degree$
  • 111.7$\degree$
  • 90$\degree$
  • 60$\degree$
Show Solution

The Correct Option is B

Solution and Explanation

Determining the C-O-C bond angle in methoxymethane (dimethyl ether) is vital for comprehending its molecular structure. Methoxymethane, an ether, features two methyl groups attached to an oxygen atom via single bonds, creating a C-O-C linkage. The oxygen atom in ethers exhibits sp3 hybridization, generally indicating a tetrahedral arrangement around it.

A perfect tetrahedral geometry possesses a bond angle of 109.5°. Nevertheless, methoxymethane's C-O-C bond angle is somewhat greater. This deviation arises because the repulsion between lone pairs and bond pairs exceeds the repulsion between bond pairs, resulting in a bond angle of approximately 111.7°.

The given choices are:

  • 108°
  • 111.7°
  • 90°
  • 60°

Of these options, the accurate C-O-C bond angle for methoxymethane is 111.7°.

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