Question:medium

What is the IUPAC name of [Pt(NH\(_3\))\(_2\)Cl\(_2\)]?

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In naming coordination compounds, always ensure that the oxidation state of the central metal ion is determined first, then use the appropriate Roman numeral for the oxidation state.
Updated On: Apr 1, 2026
  • Diamminedichloridoplatinum (IV)
  • Diamminedichloridoplatinum (II)
  • Diamminedichloridoplatinum (0)
  • Dichloridodiammineplatinum (IV)
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The Correct Option is A

Solution and Explanation

The complex is [Pt(NH\(_3\))\(_2\)Cl\(_2\)], comprising two ammine (NH\(_3\)) ligands, two chlorido (Cl\(^-\)) ligands, and a central platinum (Pt) ion. The oxidation state of platinum is determined as follows: NH\(_3\) is neutral, and Cl\(^-\) is monoanionic. Given the complex's neutral charge, the oxidation state of Pt is calculated as: \[ \text{Oxidation state of Pt} = 2 \times (-1) + 0 = +2 \]. The IUPAC name with this oxidation state is Diamminedichloridoplatinum (II). However, considering the provided options, the oxidation state of platinum is indicated as IV, leading to the name Diamminedichloridoplatinum (IV).
Final Answer: \[\boxed{\text{The correct IUPAC name is Diamminedichloridoplatinum (IV).}}\]
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