Question:medium
Two statements, one Assertion and the other Reason are given. Identify the correct option
Assertion : Primary and secondary amides on treatment with \( Br_2 \) and alcoholic \( NaOH \) yield primary and secondary amines respectively and the reaction involves stepping down the series.
Reason : The reaction occurs due to the migration of alkyl group from Carbonyl carbon atom to the Nitrogen atom with elimination of carbonyl group as the carbonate salt.
Two statements, one Assertion and the other Reason are given. Identify the correct option
Assertion : Primary and secondary amides on treatment with \( Br_2 \) and alcoholic \( NaOH \) yield primary and secondary amines respectively and the reaction involves stepping down the series.
Reason : The reaction occurs due to the migration of alkyl group from Carbonyl carbon atom to the Nitrogen atom with elimination of carbonyl group as the carbonate salt.
Assertion : Primary and secondary amides on treatment with \( Br_2 \) and alcoholic \( NaOH \) yield primary and secondary amines respectively and the reaction involves stepping down the series.
Reason : The reaction occurs due to the migration of alkyl group from Carbonyl carbon atom to the Nitrogen atom with elimination of carbonyl group as the carbonate salt.
Show Hint
Hoffmann bromamide degradation is shown by primary amides only and gives primary amines with one carbon atom less than the amide.
Updated On: May 6, 2026
- Assertion is correct but Reason is incorrect.
- Both Assertion and Reason are incorrect.
- Both Assertion and Reason are correct.
- Assertion is incorrect but Reason is correct.
Show Solution
The Correct Option is D
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