The point charges \( Q \) and \( -q \) are subjected to forces from each other and an applied electric field \( \vec{E} \). The force exerted by the electric field on charge \( -q \) is \( F_{\text{field}} = qE \), acting perpendicular to the line connecting the charges. Coulomb's law describes the force between the two charges: \( F_{\text{Coulomb}} = \frac{1}{4\pi \epsilon_0} \frac{Qq}{r^2} \). The net force on \( -q \) is the vector sum of these two forces. If \( \theta \) is the angle between the line joining the charges and the net force on \( -q \), then \( \tan \theta = \frac{F_{\text{field}}}{F_{\text{Coulomb}}} \). Substituting the force expressions yields \( \tan \theta = \frac{qE}{\frac{1}{4\pi \epsilon_0} \frac{Qq}{r^2}} \), which simplifies to \( \tan \theta = \frac{4\pi \epsilon_0 E r^2}{Q} \). Therefore, the angle \( \theta \) is given by \( \theta = \tan^{-1} \left( \frac{4\pi \epsilon_0 E r^2}{Q} \right) \).