Step 1: Plan:
Use the fact that equal potential means $\sigma R$ is equal on both spheres.
Step 2: Steps:
For a sphere, $V = \frac{\sigma R}{\varepsilon_0}$. After connection, $\sigma_a R = \sigma_b(2R)$, so the small sphere has density $2\sigma_1$ when the large one has $\sigma_1$.
Charge conservation: $4\pi R^2\sigma + 16\pi R^2\sigma = 4\pi R^2(2\sigma_1) + 16\pi R^2\sigma_1$. That is $20\sigma = 8\sigma_1 + 16\sigma_1 = 24\sigma_1$, so $\frac{\sigma_1}{\sigma} = \frac{20}{24} = \frac56$.
Final Answer:
The ratio $\sigma_1:\sigma$ is $5:6$, option (D).
\[ \boxed{5:6} \]