Step 1: Recall the path difference condition for dark fringes in YDSE.
Destructive interference occurs when path difference is an odd half-wavelength: $\Delta = (2n-1)\frac{\lambda}{2}$, $n = 1, 2, 3, \ldots$
Step 2: Identify the order of the dark fringe.
Second-order dark fringe: $n = 2$.
Step 3: Compute the path difference.
\[ \Delta = (2 \times 2 - 1)\frac{\lambda}{2} = \frac{3\lambda}{2} \]
Step 4: Convert wavelength to SI units.
$\lambda = 5000$ A $= 5 \times 10^{-7}$ m.
Step 5: Calculate the path difference in micrometres.
\[ \Delta = \frac{3 \times 5 \times 10^{-7}}{2} = 7.5 \times 10^{-7} \text{ m} = 0.75 \text{ } \mu\text{m} \]
Step 6: State the final answer.
\[ \boxed{\Delta = 0.75 \ \mu\text{m}} \]