Question:medium

The third law of thermodynamics relates to

1. The entropy of a perfect crystal at absolute zero temperature.
2. The relation between work and heat.
3. Evolution of entropy of a system with time.
4. Conservation of mass.
Choose the correct answer from the options given below:

Show Hint

The third law of thermodynamics states that at absolute zero, the entropy of a perfect crystal is zero.
Updated On: Feb 18, 2026
  • (A) only.
  • (B) only.
  • (C) only.
  • (D) only.
Show Solution

The Correct Option is A

Solution and Explanation

Step 1: Comprehend the Third Law of Thermodynamics. The third law posits that the entropy of a flawless crystal at absolute zero (0 K) equals zero. This is because the system exists in its lowest energy state at 0 K, devoid of randomness or disorder.
Step 2: Explanation of Alternative Options.
- (B): This relates to the first and second laws of thermodynamics.
- (C): The progression of entropy over time is a broader topic addressed by the second law of thermodynamics.
- (D): The law of conservation of mass, not the third law of thermodynamics, describes mass conservation.
Step 3: Summary. In summary, the third law of thermodynamics focuses on the entropy of a perfect crystal specifically at absolute zero.
Final Answer: \[ \boxed{\text{(A) only}} \]
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