Step 1: Set up the geometry.
Let \(P\) be the pole of the mirror and \(C\) its centre of curvature, so the distance \(PC\) is by definition the radius of curvature \(R\).
Step 2: Locate the focus within that geometry.
For a mirror of small aperture, the principal focus \(F\) lies exactly midway between \(P\) and \(C\), so the focal length \(f = PF\) is half of \(PC\).
Step 3: Write this as an equation and solve for R.
From \(f = R/2\), multiplying both sides by 2 gives \[ R = 2f \] which holds for concave and convex mirrors alike under the small aperture approximation.
\[ \boxed{R = 2f} \]