Step 1: {Express the given information in a mathematical format}
\[
|z + 3 - i| = 1
\]
Step 2: {Standard form of a circle equation}
\[
(x + 3)^2 + (y - 1)^2 = 1
\]
Step 3: {Determine the modulus}
Given that \( \arg(z) = \pi \), the point is situated on the negative real axis:
\[
z = -3 + 0i
\]
Step 4: {Compute the modulus}
\[
|z| = \sqrt{(-3)^2 + 0^2} = 3
\]