Question:medium

The major product of the following reaction is:
6-Phenylhepta-2,4-diene

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In elimination reactions with excess base, the most stable conjugated diene product is favored due to its resonance stability.
Updated On: Jan 14, 2026
  • 2-Phenylhepta-2,4-diene
  • 6-Phenylhepta-3,5-diene
  • 6-Phenylhepta-2,4-diene
  • 2-Phenylhepta-2,5-diene
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The Correct Option is C

Solution and Explanation

To identify the primary product of the given reaction, an analysis of the compound's structure and reactivity is necessary. The compound provided is 6-Phenylhepta-2,4-diene.

Step 1: Structural Analysis: The compound is a conjugated diene with a phenyl substituent at the sixth carbon. Its structure is characterized by:

  • A seven-carbon backbone (Hepta).
  • Double bonds located at carbons 2 and 4 (2,4-diene).
  • A phenyl group attached to carbon 6.

Step 2: Electrophilic Addition Mechanisms: Conjugated dienes, such as hepta-2,4-diene, are susceptible to undergoing either 1,2-addition (typically under kinetic control) or 1,4-addition (typically under thermodynamic control) in electrophilic addition reactions.

Step 3: Stability Assessment: Conjugation allows for electron delocalization, which stabilizes certain reaction products. Reactions involving conjugated dienes often yield products that maintain the conjugated double bond system, as observed with 6-Phenylhepta-2,4-diene. This conjugation enhances molecular stability through resonance.

OptionProduct Description
2-Phenylhepta-2,4-dienePhenyl group at position 2; differs from the input structure.
6-Phenylhepta-3,5-dieneShifted double bond positions; potentially less favored.
6-Phenylhepta-2,4-dieneThe original compound; a conjugated diene structure favored by resonance.
2-Phenylhepta-2,5-dieneNon-conjugated structure with a phenyl group at position 2.

Conclusion: The most stable and resonance-stabilized structure, identified as the major product, is 6-Phenylhepta-2,4-diene.

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