Question:medium

The major product in the following reaction is:
 

Fig. Chemical Reaction

Updated On: Mar 20, 2026
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The Correct Option is A

Solution and Explanation

The given chemical reaction involves the addition of water to an alkene in the presence of mercuric acetate, followed by reduction with sodium borohydride. This reaction is known as oxymercuration-demercuration. Let's break down the steps:

  1. Oxymercuration: The alkene undergoes electrophilic addition with mercuric acetate, Hg(OAc)2, in water. The mercuric ion adds to the less substituted carbon of the double bond, forming a mercurinium ion intermediate. Water then attacks the more substituted carbon, resulting in the formation of a Markovnikov alcohol intermediate.

  2. Demercuration: The intermediate is then reduced with sodium borohydride (NaBH4), converting the C-Hg bond to a C-H bond and yielding the alcohol as the final product.

Thus, the major product is a Markovnikov alcohol, where the hydroxyl group (-OH) is added to the more substituted carbon of the alkene.

The figure above represents the correct structure of the major product.

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